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In the stochastic approach, we strive to express some average properties of obstructions that take into account scattering (or diffuse re ections) from the rough wall surfaces and diffraction mechanisms from building rooftops and corners along the propagation paths With all advantages of the proposed physical statistical method to describe the terrain relief and overlay pro le of the buildings as well as the average signal intensity or path loss, it is clear that it cannot explain some extreme cases of receiver antennas positioned within deep shadow regions surrounded by tall buildings For such cases, the strict 2D-multiple diffraction and knife-edge models, mentioned in 4 (see also References [2,5 13]), are better predictors of the local signal strength As will be shown in Section 11.

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The intermediate species include the tight or contact ion pair (II) (also referred to as the intimate ion pair) and the solvent-separated or loose ion pair (III). The intimate ion pair has a counter- or gegenion of opposite charge close to the propagating center (unseparated by solvent). the solvent-separated ion pair involves ions that are partially separated by solvent molecules. The propagating cationic chain end has a negative counterion. For an anionic polymerization the charges in species II-IV are reversed; that is, B carries the negative charge and A the positive charge. There is a propagating anionic chain end with a positive counterion. Alternate terms used for free ion and ion pair are unpaired ion and paired ion, respectively. Most ionic polymerizations involve two types of propagating species, an ion pair and a free ion IV, coexisting in equilibrium with each other. The identity of the ion pair (i.e., whether the ion pair is best described as species II or III) depends on the particular reaction conditions, especially the solvent employed. Increased solvent polarity favors the loose ion pair while the tight ion pair predominates in solvents of low polarity. The ion pairs in cationic polymerization tend to be loose ion pairs even in solvent of low or moderate polarity since the counterions (e.g., bisulfate, SbCl , perchlorate) are typically large ions. The lower charge 6 density of a large counterion results in smaller electrostatic attractive forces between the propagating center and counterion. The nature of the ion pairs is much more solvent-dependent

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THE PREVIOUS CHAPTER showed you how to define and use typed data sets and table adapters for getting data into your Windows Forms application Now we'll get into the details of data binding to give you a solid foundation for understanding the rest of the material in the book In the past, developers often had to write a lot of custom code to present data and to take user input and put it into an underlying data source At some point people realized it would make a lot more sense to encapsulate that functionality within the user interface framework, and automatic data binding was born This chapter gives a quick introduction on how to bind sources of data to user interface controls in Windows Forms It starts with the high-level concepts behind data binding introduced in 1 and dives a little deeper into each one, including how to set up data binding from code for various types of data-bound controls using Binding objects and the new BindingSource component, which is one of the most important additions to Windows Forms data binding in NET 20

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2, in some experimental sites where antennas were located well within the shadow zone caused by nearby buildings, the median error and standard deviations between theoretical predictions and measured data are signi cant, (around 15 20 dB) Therefore, the validity and accuracy of the multiparametric stochastic approach will be established via experimental data..

in anionic polymerizations where the typical counterion (e.g., Li , Na ) is small. The covalent species I is generally ignored since it is usually unreactive (or much lower in reactivity) compared to the other species. Free-ion concentrations are generally much smaller than ionpair concentrations but the relative concentrations are greatly affected by the reaction conditions. Increased solvent polarity results in a shift from ion pairs to free ions. The nature of the solvent has a large effect in ionic polymerization since the different types of propagating species have different reactivities. Loose ion pairs are more reactive than tight ion pairs. Free ions are orders of magnitude higher in reactivity than ion pairs in anionic polymerization. Ion pairs are generally no more than an order of magnitude lower in reactivity compared to free ions in cationic polymerization. Ionic polymerizations are characterized by a wide variety of modes of initiation and termination. Unlike radical polymerization, termination in ionic polymerization never involves the bimolecular reaction between two propagating polymer chains of like charge. Termination of a propagating chain occurs by its reaction with the counterion, solvent, or other species present in the reaction system.

Various initiators can be used to bring about the polymerization of monomers with electronreleasing substituents [Faust and Shaffer, 1997; Gandini and Cheradame, 1980, 1985; Kennedy and Marechal, 1982; Matyjaszewski and Pugh, 1996; Sauvet and Sigwalt, 1989]. Additional information on cationic initiators is described in Chap. 7. 5-2a-1 Protonic Acids

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